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Bauxite Information

Bauxite is an aluminium ore and is the main source of aluminium. This form of rock consists mostly of the minerals gibbsite Al(OH)3, boehmite γ-AlO(OH), and diaspore α-AlO(OH), in a mixture with the two iron oxides goethite and hematite, the clay mineral kaolinite, and small amounts of anatase TiO2. Bauxite was named after the village Les Baux in southern France, where it was first recognised as containing aluminium and named by the French geologist Pierre Berthier in 1821.

Contents

Bauxite formation

Lateritic bauxites (silicate bauxites) are distinguished from karst bauxite ores (carbonate bauxites). The early discovered carbonate bauxites occur predominantly in Europe and Jamaica above carbonate rocks (limestone and dolomite), where they were formed by lateritic weathering and residual accumulation of intercalated clays or by clay dissolution residues of the limestone.

The lateritic bauxites are found mostly in the countries of the tropics.They were formed by lateritization (see laterite) of various silicate rocks such as granite, gneiss, basalt, syenite, and shale. In comparison with the iron-rich laterites, the formation of bauxites demands even more on intense weathering conditions in a location with very good drainage. This enables the dissolution of the kaolinite and the precipitation of the gibbsite. Zones with highest aluminium content are frequently located below a ferruginous surface layer. The aluminium hydroxide in the lateritic bauxite deposits is almost exclusively gibbsite.

Production trends

Bauxite output in 2005

In 2007, Australia was one of the top producers of bauxite with almost one-third of the world's production, followed by China, Brazil, Guinea, and India. Although aluminium demand is rapidly increasing, known reserves of its bauxite ore are sufficient to meet the worldwide demands for aluminium for many centuries. Increased aluminium recycling, which has the advantage of lowering the cost in electric power in producing aluminium, will considerably extend the world's bauxite reserves.

estimated Numbers for 2008's total proven bauxite reserves x1000 tonne[1]
Country Mine production Reserves Reserve base
2007 2008
Guinea 18,000 18,000 7,400,000 8,600,000
Australia 62,400 63,000 5,800,000 7,900,000
Vietnam 30 30 2,100,000 5,400,000
Jamaica 14,600 15,000 2,000,000 2,500,000
Brazil 24,800 25,000 1,900,000 2,500,000
Guyana 1,600 1,600 700,000 900,000
India 19,200 20,000 770,000 1,400,000
China 30,000 32,000 700,000 2,300,000
Greece 2,220 2,200 600,000 650,000
Iran 500[2]
Suriname 4,900 4,500 580,000 600,000
Kazakhstan 4,800 4,800 360,000 450,000
Venezuela 5,900 5,900 320,000 350,000
Russia 6,400 6,400 200,000 250,000
United States NA NA 20,000 40,000
Other countries 7,150 6,800 3,200,000 3,800,000
World total (rounded) 202,000 205,000 27,000,000 38,000,000

In November 2010, Nguyen Tan Dung, the prime minister of Vietnam, announced that Vietnam's bauxite reserves might total 11000Mt; this would be the largest in the world.[3]

Processing

Bauxite being loaded at Cabo Rojo, Dominican Republic, to be shipped elsewhere for processing; 2007

Bauxite is usually strip mined because it is almost always found near the surface of the terrain, with little or no overburden. Approximately 75% to 85% of the world's bauxite production is processed first into alumina, and then into aluminium by electrolysis. Bauxite rocks are typically classified according to their intended commercial application: metallurgical, abrasive, cement, chemical, and refractory.

Usually, bauxite ore is heated in a pressure vessel along with a sodium hydroxide solution at a temperature of 150 to 200 °C. At these temperatures, the aluminium is dissolved as an aluminate (the Bayer process). After separation of ferruginous residue (red mud) by filtering, pure gibbsite is precipitated when the liquid is cooled, and then seeded with fine-grained aluminium hydroxide. The gibbsite is usually converted into aluminium oxide, Al2O3, by heating. This mineral becomes molten at a temperature of about 1000 °C, when the mineral cryolite is added as a flux. Next, this molten substance can yield metallic aluminium by passing an electric current through it in the process of electrolysis, which is called the Hall–Héroult process after its American and French discoverers in 1886.

Prior to the Hall–Héroult process, elemental aluminium was made by heating ore along with elemental sodium or potassium in a vacuum. The method was complicated and consumed materials that were themselves expensive at that time. This made early elemental aluminium more expensive than gold.[4]

See also

Book: Aluminium
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Notes

  1. ^ U.S. Geological Survey, Mineral Commodity Summaries, January 2009
  2. ^ http://www.bgs.ac.uk/mineralsuk/commodity/world/home.html
  3. ^ "Mining Journal - Vietnam’s bauxite reserves may total 11 billion tonnes". http://www.mining-journal.com/exploration--and--development/vietnams-bauxite-reserves-may-total-11-billion-tonnes. Retrieved 2010-11-28.
  4. ^ http://www.worldwidewords.org/articles/aluminium.htm Aluminium versus aluminum Author: Michael Quinion, 1996–2011

References

External links

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